Notation /xiChapter 1Overview of Chemical Reaction Engineering /1
Part IHomogeneous Reactions in IdealReactors
Chapter 2Kinetics of Homogeneous Reactions /132.1 Concentration-Dependent Term of a Rate Equation /142.2 Temperature-Dependent Term of a Rate Equation /272.3 Searching for a Mechanism 2.4 Predictability of Reaction Rate from Theory 27
Chapter 3 Interpretation of Batch Reactor Data /383.1 Constant-volume Batch Reactor /393.2 Varying-volume Batch Reactor /693.3 Temperature and Reaction Rate /723.4 The Search for a Rate Equation /75
Chapter 4 Introduction to Reactor Design /83
Chapter 5Ideal Reactors for a Single Reaction /90 5.1 Ideal Batch Reactors /905.2 Steady-State Mixed Flow Reactors /945.3 Steady-State Plug Flow Reactors /101
Chapter 6Design for Single Reactions /120 6.1 Size Comparison of Single Reactors /121 6.2 Multiple-Reactor Systems /124 6.3 Recycle Reactor /136 6.4 Autocatalytic Reactions /140
Chapter 7Design for Parallel Reactions /152Chapter 8 Potpourri of Multiple Reactions /170 8.1 Irreversible First-Order Reactions in Series /170 8.2 First-Order Followed by Zero-Order Reaction /178 8.3 Zero-Order Followed by First-Order Reaction /179 8.4 Successive Irreversible Reactions of Different Orders /180 8.5 Reversible Reactions /181 8.6 Irreversible Series-Parallel Reactions /181 8.7 The Denbigh Reaction and its Special Cases /194
Chapter 9Temperature and Pressure Effects /207 9.1 Single Reactions /207 9.2 Multiple Reactions /235
Chapter 10Choosing the Right Kind of Reactor /240
Part IIFlow Patterns, Contacting, and Non-IdealFlow /255
Chapter 11Basics of Non-Ideal Flow /257 11.1 E, the Age Distribution of Fluid , the RTD /260 11.2 Conversion in Non-Ideal Flow Reactors /273
Chapter 12Compartment Models /283
Chapter 13The Dispersion Model /293 13.1 Axial Dispersion /293 13.2 Correlations for Axial Dispersion /309 13.3 Chemical Reaction and Dispersion /312 Chapter 14The Tanks-Series Model /321 14.1 Pulse Response Experiments and the RTD /321 14.2 Chemical Conversion /328Chapter 15The Convection Model for Laminar Flow /339 15.1 The Convection Model and its RTD /339 15.2 Chemical Conversion in Laminar Flow Reactors /345 Chapter 16Earliness of Mixing, Segregation and RTD /350 16.1 Self-mixing of a Single Fluid /350 16.2 Mixing of Two Miscible Fluids /361
Part IIIReactions Catalyzed by Solids /367
Chapter 17Heterogeneous Reactions - Introduction /369
Chapter 18Solid Catalyzed Reactions /37618.1 The Rate Equation for Surface Kinetics /37918.2 Pore Diffusion Resistance Combined with Surface Kinetics /38118.3 Porous Catalyst Particles /38518.4 Heat Effects During Reaction /39118.5 Performance Equations for Reactors Containing Porous Catalyst Particles /39318.6 Experimental Methods for Finding Rates /39618.7 Product Distribution in Multiple Reactions /140
Chapter 19The Packed Bed Catalytic Reactor /427
Chapter 20Reactors with Suspended Solid Catalyst . Fluidized Reactors of Various Types /447 20.1 Background Information About Suspended Solids Reactors /447 20.2 The Bubbling Fluidized Bed—BFB /451 20.3 The K-L Model for BFB /445 20.4 The Circulating Fluidized Bed—CFB /470 20.5 The Jet Impact Reactor /470
Chapter 21Deactivating Catalysts /47321.1 Mechanisms of Catalyst Deactivation /47421.2 The Rate and Performance Equations /47521.3 Design /489
Chapter 22G/L Reactions on Solid Catalyst: Trickle Beds , SlurryReactors , Three-Phase Fluidized Beds /50022.1 The General Rate Equation /50022.2 Performanc Equations for an Excess of B /50322.3 Performance Equations for an Excess of A /50922.4 Which Kind of Contactor Use /50922.5 Applications /510
Part IVNon-Catalytic Systems /521Chapter 23Fluid-Fluid Reactions : Kinetics /523 23.1 The Rate Equation /524
Chapter 24Fluid-Fluid Reactors : Design /540 24.1 Straight Mass Transfer /543 24.2 Mass Transfer Plus Not Very Slow Reaction /546
Chapter 25Fluid-Particle Reactions : Kinetics /566 25.1 Selection of a Model /56825.2 Shrinking Core Model for Spherical Particles of UnchangingSize /570 25.3 Rate of Reaction for Shrinking Spherical Particles /577 25.4 Extensions /579 25.5 Determination of the Rate-Controlling Step /582
Chapter 26Fluid-Particle Reactors : Design /589Part VBiochemical Reaction Systems /609
Chapter 27