PREFACE
1 BASIC CONCEPTS AND DEFINITIONS
1-1 The Nature of Thermodynamics
1-2 Dimensions and Units
1-3 System, Property, and State
1-4 Density, Specific Volume, and Specific Gravity
1-5 Pressure
1-6 The Zeroth Law and Temperature
1-7 Problem-Solving Techniques
1-8 Summary
Problems
2 THE FIRST LAW OF THERMODYNAMICS
2-1 Concepts of Work and Energy
2-2 The First Law of Thermodynamics
2-3 A Conservation of Energy Principle for Closed Systems
2-4 The Nature of the Energy E
2-5 Heat Transfer
2-6 Expansion and Compression Work
2-7 Elastic Spring Work
2-8 Other Quasiequilibrium Work Interactions
2-9 Summary
Problems
3 PROPERTIES OF A PURE, SIMPLE COMPRESSIBLE SUBSTANCE
3-1 The State Postulate and Simple Systems
3-2 The PvT Surface
3-3 The Pressure-Temperature Diagram
3-4 The Pressure-Specific Volume Diagram
3-5 The Temperature-Specific Volume Diagram
3-6 Tables of Properties of Pure Substances
3-7 Tabular Data and Closed-System Energy Analysis
3-8 The Specific Heats
3-9 Summary
3-10 Appendix: Fundamentals of Partial Derivatives
Problems
4 THE IDEAL GAS, CORRESPONDING STATES, AND INCOMPRESSIBLE MODELS
4-1 Ideal-Gas Equation of State
4-2 Internal Energy, Enthalpy, and Specific-Heat Relations for
Ideal Gases
4-3 Specific Heats of Ideal Gases
4-4 Energy Analysis of Closed Ideal-Gas Systems
4-5 The Compressibility Factor and the Corresponding States Principle
4-6 Property Relations for Incompressible Substances
4-7 Summary
Problems
6 CONTROL-VOLUME ENERGY ANALYSIS
5-1 Introduction
5-2 Conservation of Mass Principle for a Control Volume
5-3 Conservation of Energy Principle for a Control Volume
5-4 Steady-State Control-Volume Energy Equations
5-5 Comments on Problem-Solving Techniques
5-6 Engineering Applications Involving Steady-State Control Volumes
5-7 Introduction to Thermodynamic Cycles
5-8 Transient (Unsteady) Flow Analysis
5-9 Summary
Problems
6 THE SECOND LAW AND ENTROPY
6-1 Introduction
6-2 Heat Engines, Refrigerators, and Heat Pumps
6-3 Second-Law Statements
6-4 Reversible and Irreversible Processes
6-5 The Second Law and Entropy--Classical Presentation
6-5-1 Analytical Forms of the Kelvin-Planck Statement
6-5-2 General Second-Law Limitations for Heat Engines
6-5-3 The Thermodynamic Temperature Scale
6-5-4 Performance Standards for Reversible Heat Engines
6-5-5 The Clausius Inequality
6-5-6 The Entropy Function
6-5-7 Entropy Generation and the Closed-System Entropy Balance
6-6 The Second Law and Entropy--Alternate Presentation
6-6-1 The Second-Law Postulate
6-6-2 An Entropy Balance for a Closed System
6-6-3 The Thermodynamic Temperature Scale and the Carnot Efficiency
7 EVALUATION OF ENTROPY CHANGE AND THE CONTROL-VOLUME ENTROPY BALANCE
8 SOME CONSEPUENCES OF THE SECOND LAW
9 AVAILABILITY(EXERGY)AND IRREVERSIBILITY
10 NONREACTIVE IDEAL-GAS MIXTURES
11 PVT BEHAVIOR OF REAL GASES AND REAL-GAS
12 GENERALIZED THERMODYNAMIC RELATIONSHIPS
13 CHEMICAL REACTIONS
14 CHEMICAL EPUILIBRIUM
15 REFRIGERATION SYSTEMS
A-1 SUPPLEMENTARY TABLES AND FIGURES(SI UNITS)
A-2 SUPPLEMENTARY TABLES AND FIGURES(USCS UNITS)
A-3 INTRODUCTION TO EES
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