Chapter 1 Introduction
1.1 History of Chemistry
1.2 Chemistry in Medicine
1.3 Measurement of Matter: the SI Unit
1.4 Quantitative Ways of Expressing Concentration
1.5 Chapter Summary
Review Questions
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References
Chapter 2 Colligative Properties of Dilute Solutions
2.1 Vapor Pressure Lowering
2.2 Boiling Point Elevation and Freezing Point Depression
2.3 Osmotic Pressure
2.4 Chapter Summary
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References
Chapter 3 Solution Electrolyte
3.1 Theory of Strong Electrolyte Solution
3.2 Proton Theory of Acids and Bases
3.3 Calculating the pH of Acid and Base Solution
3.4 Chapter Summary
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References
Chapter 4 Buffer Solution
4.1 Buffer Solution and How a Buffer Works
4.2 Calculating the pH of a Buffer Solution
4.3 Buffer Capacity and Buffer Range
4.4 Preparing Buffer Solutions
4.5 Buffer Solution in Human Blood
4.6 Chapter Summary
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References
Chapter 5 Equilibria of Sparingly Soluble Ionic Compounds
5.1 The Solubility Product Constant, Ksp
5.2 The Relationship between Solubility and Ksp
5.3 Predicting the Formation of a Precipitate: Q vs. Ksp
5.4 Equilibria Shift
5.5 Application of Ionic Equilibria to Medicine
5.6 Chapter Summary
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References
Chapter 6 Colloids and Emulsions
6.1 Introduction
6.2 Colloid
6.3 Sol
6.4 Polymer Solution
6.5 Chapter Summary
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Chapter 7 Chemical Thermodynamics
7.1 The First Law: The Concepts
7.2 The Extent of Chemical Reactions
7.3 Indirect Determination of AH: Hess's Law
7.4 Energy Values of Food
7.5 Chapter Summary
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Chapter 8 The Direction and of Chemical Reactions Equilibrium
8.1 Spontaneity: The Meaning of Spontaneous Change
8.2 Entropy and Entropy Change
8.3 Free Energy and Free Energy Change
8.4 Standard Free Energy Change, AGe
8.5 Relationship of AGe to AG for Nonstandard Conditions
8.6 Relationship ofAGe to the Equilibrium Constant Ke
8.7 Criteria for Spontaneous Change
8.8 Altering Equilibrium Conditions: Le Ch~terlier's Principle
8.9 The Le Chfitelier's Principle in Physiology
8.1 0 Chapter Summary
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Chapter 9 Kinetics: Rates and Mechanisms of Chemical Reactions
9.1 The Rates of Chemical Reactions
9.2 Rate Laws and Reaction Order
9.3 Rate Constant and Reaction Order
9.4 Reaction Mechanisms: Steps in the Overall Reaction
9.5 Theoretical Models for Chemical Kinetics
9.6 The Effect of Temperature on Reaction Rates
9.7 Catalysis
9.8 Chapter Summary
Review Questions
Chapter 10 Electrochemistry
10.1 Oxidation-Reduction Reactions
10.2 Voltaic Cell
10.3 Electrode Potentials
10.4 Free Energy and Electrical Work
10.5 Predicting Spontaneous Reactions for Nonstandard Conditions
10.6 Chapter Summary
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Chapter 11 Atomic Structure and Periodical Table
11.1 The Discovery of Atomic Structure
11.2 Atomic Spectrum and the Bohr Model of the Atom
11.3 The Wave-Particle Duality of Matter and Energy
11.4 The Atomic Orbital and the Probable Location of the Electron
11.5 Quantum Numbers and Electron Orbitals
11.6 Electron Configurations
11.7 The Periodic Law and the Periodic Table
11.8 Chapter Summary
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Chapter 12 Covalent and Intermolecular Forces Bonding
12.1 The Covalent Bonding Model
12.2 Hybridization of Atomic Orbitals
12.3 Molecular Orbital (MO) Theory
12.4 Delocalized Electrons: Bonding in the Benzene Molecule
12.5 Intermolecular Forces
12.6 Chapter Summary
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Chapter 13 Chemistry Compounds of Coordination
13.1 The Structure of Complexes
13.2 Formulas and Names of Coordination Complexes
13.3 Isomerism
13.4 Chemical Bond Theories of Complexes
13.5 Aspects of Complex-Ion Equilibrium
13.6 Metals and Chelates in Living Systems
13.7 Chapter Summary
Review Questions
Chapter 14 Acid-Base Titration
14.1 Getting Started: Some Terminology
14.2 Significant Figures
14.3 Acid-Base Indicator
14.4 Titration of a Strong Acid with a Strong Base
14.5 Titration of a Weak Acid with a Strong Base
14.6 Standardization of Acid (Base) Using a Primary Standard
14.7 Chapter Summary
Review Questions
Chapter 15 Absorption Spectroscopy UV-Vis
15.1 UV-Vis Spectroscopic Regions
15.2 Beer-Lambert Law
15.3 UV/Vis Absorbance Bands and Structures
Review Questions
Notes
Index
Appendix A--H