Preface
Chapter 1 THERMODYNAMICS
1.1 Physical Chemistry
1.2 Thermodynamics
1.3 Temperature
1.4 The Mole
1.5 Ideal Gases
1.6 Differential Calculus
1.7 Equations of State
1.8 Integral Calculus
1.9 Study Suggestions
1.10 Summary
Chapter 2 THE FIRST LAW OF THERMODYNAMICS
2.1 Classical Mechanics
2.2 P-V Work
2.3 Heat
2.4 The First Law of Thermodynamics
2.5 Enthalpy
2.6 Heat Capacities
2.7 The Joule and Joule-Thomson Experiments
2.8 Perfect Gases and the First Law
2.9 Calculation of First-Law Quantities
2.10 State Functions and Line Integrals
2.11 The Molecular Nature of Internal Energy
2.12 Problem Solving
2.13 Summary
Chapter 3 THE SECOND LAW OF THERMODYNAMICS
3.1 The Second Law of Thermodynamics
3.2 Heat Engines
3.3 Entropy
3.4 Calculation of Entropy Changes
3.5 Entropy, Reversibility, and Irreversibility
3.6 The Thermodynamic Temperature Scale
3.7 What Is Entropy？
3.8 Entropy, Time, and Cosmology
3.9 Summary
Chapter 4 MATERIAL EQUILIBRIUM
4.1 Material Equilibrium
4.2 Entropy and Equilibrium
4.3 The Gibbs and Helmholtz Energies
4.4 Thermodynamic Relations for a System in Equilibrium
4.5 Calculation of Changes in State Functions
4.6 Chemical Potentials and Material Equilibrium
4.7 Phase Equilibrium
4.8 Reaction Equilibrium
4.9 Entropy and Life
4.10 Summary
Chapter 5 STANDARD THERMODYNAMIC FUNCTIONS OF REACTION
5.1 Standard States of Pure Substances
5.2 Standard Enthalpy of Reaction
5.3 Standard Enthalpy of Formation
5.4 Determination of Standard Enthalpies of Formation and Reaction
5.5 Temperature Dependence of Reaction Heats
5.6 Use of a Spreadsheet to Obtain a Polynomial Fit
5.7 Conventional Entropies and the Third Law
5.8 Standard Gibbs Energy of Reaction
5.9 Thermodynamics Tables
5.10 Estimation of Thermodynamic Properties
5.11 The Unattainability of Absolute Zero
5.12 Summary
Chapter 6 REACTION EQUILIBRIUM IN IDEAL GAS MIXTURES
6.1 Chemical Potentials in an Ideal Gas Mixture
6.2 Ideal-Gas Reaction Equilibrium
6.3 Temperature Dependence of the Equilibrium Constant
6.4 Ideal-Gas Equilibrium Calculations
6.5 Simultaneous Equilibria
6.6 Shifts in Ideal-Gas Reaction Equilibria
6.7 Summary
Chapter 7 ONE-COMPONENT PHASE EQUILIBRIUM AND SURFACES
7.1 The Phase Rule
7.2 One-Component Phase Equilibrium
7.3 The Clapeyron Equation
7.4 Solid-Solid Phase Transitions.
……
Chapter 8 REAL GASES
Chapter 9 SOLUTIONS
Chapter 10 NONIDEAL SOLUTIONS
Chapter 11 REACTION EQUILIBRIUM IN NONIDEAL SYSTEMS
Chapter 12 MULTICOMPONENT PHASE EQUILIBRIUM
Chapter 13 ELECTROCHEMICAL SYSTEMS
Chapter 14 KINFTIC THEORY OF GASES
Chapter 15 TRANSPORT PROCESSES
Chapter 16 REACTION KINETICS
Chapter 17 QUANTUM MECHANICS
Chapter 18 ATOMIC STRUCTURE
Chapter 19 MOLECULAR ELECTRONIC STRUCTURE
Chapter 20 SPECTROSCOPY AND PHOTOCHEMISTRY
Chapter 21 STATISTICAL MECHANICS
Chapter 22 THEORIES OF REACTION RATES
Chapter 23 SOLIDS AND LIQUIDS
Bibliography
Appendix
Answers to Selected Problems
Index
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