有机合成百题精解

第一章 解答有机合成题的基础知识准备················································································ 1
一、烃类和简单杂环的官能团化····························································································· 1
二、官能团的转换················································································································ 6
三、复习和熟练掌握碳链的增长方法······················································································ 9
四、熟悉一些重要的重排反应······························································································ 10
五、掌握碳碳键的构建方法·································································································· 10
六、掌握化学键的切断与逆合成分析法················································································· 10
七、熟悉按照化学键异裂方式切断后的常见合成子及其对应的等价物······································· 10
八、逆合成分析切断法的技巧······························································································ 11
九、一条理想的合成路线的确定需要把握的几点···································································· 11
第二章 有机化合物常见增长和缩短碳链的方法····································································· 12
第一节 增长碳链的方法····································································································· 12
一、增加一个碳原子的常见方法··························································································· 12
二、增加两个碳原子的常见方法··························································································· 16
三、增加三个碳原子的常见方法··························································································· 19
四、增加四个碳原子的常见方法··························································································· 22
五、碳链倍增法·················································································································· 22
第二节 缩短碳链的方法····································································································· 24
一、减少一个碳原子的常见方法··························································································· 24
二、烯烃通过氧化断键减少一个或多个碳的方法···································································· 25
第三章 有机合成练习题题解······························································································· 26
参考文献·························································································································· 238