有机化学实验（英汉双语版）

目录
前言
第1章 有机化学实验基础知识 1
1.1 有机化学实验基本规则 1
1.2 有机化学实验安全常识 2
1.3 有机化学实验常用玻璃仪器和实验装置 5
1.4 有机化学文献 7
1.5 有机化学实验预习和报告 9
Chapter 1 Introduction of Organic Chemistry Experiments 13
1.1 General Rules for Organic Chemistry Experiments 13
1.2 General Knowledge for Organic Chemistry Laboratory Safety 14
1.3 Common Glass Instruments and Apparatuses for Organic Chemistry Experiments 19
1.4 Organic Chemistry Literature 21
1.5 Experimental Preview Records and Laboratory Reports on Organic Chemistry 24
第2章 有机化学实验基本操作 29
2.1 玻璃仪器的洗涤与干燥 29
2.2 加热与冷却 30
2.3 重结晶与过滤 32
2.4 萃取与洗涤 36
2.5 干燥与干燥剂 37
2.6 蒸馏、分馏与回流 40
2.7 升华 41
2.8 色谱法 42
Chapter 2 Basic Techniques of Organic Chemistry Experiments 47
2.1 Washing and Drying of Glassware 47
2.2 Heating and Cooling 48
2.3 Recrystallization and Filtration 52
2.4 Extraction and Washing 57
2.5 Drying and Drying Agents 59
2.6 Simple Distillation，Fractional Distillation and Reflux 62
2.7 Sublimation 64
2.8 Chromatography 65
第3章 有机化学综合实验 72
Chapter 3 Comprehensive Experiments of Organic Chemistry 72
第一部分 天然产物提取与分离 72
Part 1 Extraction and Separation of Natural Products 72
3.1 咖啡因提取与分离 72
3.1 Extraction and Separation of Caffeine 73
3.2 果皮中有效成分提取与分离 75
3.2 Extraction and Separation of Effective Components from Pericarp 76
3.3 香精油的提取与分离 78
3.3 Extraction and Separation of Essential Oils 79
3.4 纸色谱分离、鉴定氨基酸 81
3.4 Separation and Identification of Amino Acids by Paper Chromatography 82
3.5 纸电泳分离、鉴定氨基酸 84
3.5 Separation and Identification of Amino Acids by Paper Electrophoresis 84
3.6 薄层色谱法分离、鉴定叶绿素 87
3.6 Separation and Identification of Chlorophyll by Thin-Layer Chromatography 88
第二部分 有机化合物的制备 90
Part 2 Preparation for Organic Compounds 90
3.7 甲基橙的制备 90
3.7 Preparation for Methyl Orange 91
3.8 乙酸异戊酯的制备 94
3.8 Preparation for Isoamyl Acetate 95
3.9 乙酰水杨酸的制备 97
3.9 Preparation for Acetylsalicylic Acid 98
3.10 二苄叉丙酮的制备 101
3.10 Preparation for Dibenzylideneacetone 102
3.11 纳迪克酸酐的制备 104
3.11 Preparation for Nadic Anhydride 105
3.12 无水乙醇的制备 107
3.12 Preparation for Absolute Ethanol 107
第三部分 有机合成新方法 109
Part 3 New Methods of Organic Synthesis 109
3.13 微波辅助合成反应——二苯乙炔的合成 109
3.13 Microwave-Assisted Synthesis Reaction——Synthesis of Diphenylacetylene 110
3.14 超声波辐射反应——苯亚甲基苯乙酮的合成 112
3.14 Ultrasonic Radiation Reaction——Synthesis of Benzyl Acetophenone 113
3.15 有机光化学反应——苯频哪醇的合成 115
3.15 Organic Photochemical Reaction——Synthesis of Benzopinacol 116
3.16 有机电化学反应——碘仿的合成 118
3.16 Organic Electrochemical Reaction——Synthesis of Iodoform 118
第四部分 有机化合物物理常数的测定及官能团鉴定 120
Part 4 Identification of Organic Compounds by Determination of Physical Constants and Characteristic Reactions 120
3.17 固体有机物熔点测定 120
3.17 Determining the Melting Point of Organic Solids 122
3.18 液体有机物折光率测定 127
3.18 Determining the Refractive Index of Organic Liquids 128
3.19 液体有机物比旋光度测定 131
3.19 Determining the Specific Rotation of Organic Liquids 132
3.20 有机化合物官能团鉴定实验 135
3.20 Identification of Organic Compounds 138
参考文献 143
References 143
附录 144
Appendix 144