增塑剂绿色催化技术（英文版）

Contents
1　Introduction　1
1.1　Background　1
1.2　Fundamentals of Plasticizers　6
1.2.1　Symbols and Abbreviations　6
1.2.2　Major Functions of Plasticizers　6
1.2.3　Major Performance-Determining Factors for Plasticizers　10
1.2.4　Mechanism for Plasticity Increase by Plasticizers　11
1.2.5　Property Requirements for Plasticizers　13
1.2.6　Inspection Standards for Plasticizers　18
1.2.7　Types of Plasticizers　18
1.3　Cyclohexane-1， 2-Dicarboxylate Plasticizers　22
1.4　Environmentally Friendly Plasticizers　25
1.5　Developmental Direction of Plasticizer Industry in China　26
1.6　Main Contents of This Book　27
References　27
2　Foreign and Domestic Plasticizer Laws　33
2.1　Foreign Plasticizer Laws， Evolution　33
2.2　Domestic Plasticizer Laws and Evolution　33
2.3　Interpretations of Foreign and Domestic Plasticizer Laws　37
2.3.1　EU Bans　37
2.3.2　EU’s REACH Policy [1，2]　39
2.3.3　The EU’s RoHS [1，3]　40
2.3.4　USA’s CPSIA　42
2.3.5　Related Phthalate Laws in Other Countries　44
2.3.6　Domestic Laws [4–6]　44
2.4　Comparison and Trend of Plasticizer Laws for Food Contact Applications　47
2.4.1　Current Status　47
2.4.2　Chinese Laws and Regulations　47
2.4.3　EU’s Laws and Regulations　47
2.4.4　USA’s Laws and Regulations　48
2.5　Conclusion　48
References　49
3　Current Status of Plasticizer Research　51
3.1　Foreign Research Status　51
3.1.1　Phthalate Hydrogenation Technology　51
3.1.2　Research on Toxicity of Phthalate Compounds　55
3.2　Domestic Research Status　55
3.2.1　Synthesis of DIBCH(1999)[9]　55
3.2.2　Synthesis of HHPA(2000)[10]　57
3.3　Di(2-Propylheptyl) Phthalate (2006) [13]　59
3.3.1　Physical Properties　59
3.3.2　Performance　60
3.4　Cyclohexane Dicarboxylate Plasticizers (2010)[14]　64
3.4.1　Preparation of Cyclohexane Dicarboxylate Plasticizers　65
3.4.2　Properties and Assessment of Cyclohexane Dicarboxylate Plasticizers　66
3.4.3　Application Examples of Formulation　71
3.4.4　Conclusion　72
3.5　Development Status of Plasticizers (2010， 2011) [18，19]　73
3.5.1　Status of Plasticizers in Foreign Countries　73
3.5.2　Status of Plasticizers in China　73
3.5.3　New Environmentally Friendly Plasticizers　75
3.5.4　Sustainable Development of Plasticizers in China　75
3.6　Diisononyl Cyclohexane-1，2-Dicarboxylate(2010，2014)[20，21]　76
3.6.1　Physical Properties　77
3.6.2　Production Routes of DINCH　77
3.6.3　Applications of DINCH　79
3.7　Environmentally Friendly Plasticizers　81
3.7.1　Di(2-Ethylhexyl) Cyclohexane-1，2-Dicarboxylate Plasticizer(2011)[22]　81
3.7.2　Research and Application Progress of Catalytic Synthesis of Environmentally Friendly Plasticizers(2012)[15]　83
3.7.3　Innovations and Applications of Green Plasticizers[97]　91
3.7.4　Technological Innovation and Market Dynamics of Green Plasticizers(2017)[98]　93
3.8　Hydrogenation of Dioctyl Phthalate (2012)[34]　94
3.9　Liquid-Phase Catalytic DOP Hydrogenation and Kinetics(2012)[50]　94
3.10　Synthesis and Application of Environmentally Friendly DEHCH Plasticizer(2013)[38，113，114]　97
3.11　Synthesis and Application of Environmentally Friendly DEHCH Plasticizer(2014–2015)　100
3.11.1　Preparation of DOP Hydrogenation Catalyst(2014)[120]　100
3.11.2　DEHP Hydrogenation Product Analysis Using GC-MC (2015)[42]　100
3.12　Synthesis of DEHCH via Direct Esterification (2015)[121]　103
3.13　Cable Industry’s Response to EU’s Newest Environmental Laws　108
3.14　Applications of Environmentally Friendly Plasticizers in Disposable Gloves(2016)[127]　108
3.15　Development and Application of Environmentally Friendly Polyester Plasticizers (2016)[128]　109
3.16　How to Accurately Assess and Use Benzoate-Based Plasticizers?(2016)[129]　110
3.17　Production Study of Environmentally Friendly DEHCH Plasticizer(2016)[130]　113
3.18　Co-existing Opportunities and Challenges for DOP Market(2017)[115]　115
3.19　Conclusion　117
References　122
4　Foreign and Domestic Inventions and Patents　129
4.1　Foreign Inventions and Patents　129
4.1.1　Hydrogenation Methods　129
4.1.2　Esterification Methods　133
4.2　Domestic Inventions and Patents　134
4.2.1　A Catalyst for Hydrogenating Dimethyl Terephthalates to Dimethyl Cyclohexane-1，4-Dicarboxylates and the Preparation Thereof(2001)[11]　134
4.2.2　A Plasticizer Containing Cyclohexane Multi-carboxylate and its Preparation Method(2006)[12]　135
4.2.3　A Catalyst for Preparing Cyclohexane-1，2-Dicarbolxylates(2008)[13]　136
4.2.4　A Method for Preparing Cyclohexane-1，2-Dicarboxylates (2008)[14]　137
4.2.5　A Method for Preparing Environmentally Friendly Di(2-ethylhexyl) Cyclohexane-1，2-Dicarboxylate(DEHCH)(2009)[15]　139
4.2.6　A Method for Preparing Environmentally Friendly Di(2-ethylhexyl) Cyclohexane-1，2-Dicarboxylate(DEHCH)Plasticizer(2011)[16]　140
4.2.7　A Method for Preparing Cyclohexane-1，2-Dicarboxylates Using Organic Acid Catalysts(2010)[17]　141
4.2.8　A Method for Preparing Cyclohexane-1，2