第1章 MOLE BALANCES \n
摩尔衡算 1 \n
1.1 The Rate of Reaction，－rA \n
反应速率 －rA 4 \n
1.2 The General Mole Balance Equation (GMBE) \n
通用摩尔衡算方程（GMBE） 8 \n
1.3 Batch Reactors (BRs) \n
间歇反应器（BRs） 10 \n
1.4 Continuous-Flow Reactors \n
连续流动反应器 12 \n
1.4.1 Continuous-Stirred Tank Reactor (CSTR) \n
全混釜（CSTR） 12 \n
1.4.2 Tubular Reactor \n
管式反应器 14 \n
1.4.3 Packed-Bed Reactor (PBR) \n
填充床反应器（PBR） 18 \n
1.4.4 Well-Mixed “Fluidized” Catalytic Bed Reactor \n
全混“流化”催化反应器 20 \n
1.5 Industrial Reactors \n
工业反应器 24 \n
1.6 And Now… A Word from Our Sponsor—Safety1 (AWFOS-S1 Safety) \n
安全案例1——学习过程安全的重要性 25 \n
1.6.1 What Is Chemical Process Safety \n
什么是化学过程安全 25 \n
1.6.2 Why Study Process Safety \n
为什么研究过程安全 25 \n
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第2章 CONVERSION AND REACTOR SIZING \n
转化率和反应器尺寸 35 \n
2.1 Definition of Conversion \n
转化率的定义 36 \n
2.2 Batch Reactor Design Equations \n
间歇反应器设计方程 36 \n
2.3 Design Equations for Flow Reactors \n
流动反应器设计方程 39 \n
2.3.1 CSTR (Also Known as a Backmix Reactor or a Vat) \n
全混釜（CSTR，一种返混或釜式反应器） 40 \n
2.3.2 Tubular Flow Reactor (PFR) \n
管式反应器（PFR） 40 \n
2.3.3 Packed-Bed Reactor (PBR) \n
填充床反应器（PBR） 41 \n
2.4 Sizing Continuous-Flow Reactors \n
确定连续流动反应器尺寸 42 \n
2.5 Reactors in Series \n
反应器串联 51 \n
2.5.1 CSTRs in Series \n
全混釜串联 52 \n
2.5.2 PFRs in Series \n
平推流反应器串联 56 \n
2.5.3 Combinations of CSTRs and PFRs in Series \n
全混釜和平推流反应器串联 57 \n
2.5.4 Comparing the CSTR and PFR Volumes and Reactor Sequencing \n
比较全混釜和平推流反应器的尺寸以及反应器顺序 61 \n
2.6 Some Further Definitions \n
其他定义 62 \n
2.6.1 Space Time \n
空时 62 \n
2.6.2 Space Velocity \n
空速 64 \n
2.7 And Now… A Word from Our Sponsor—Safety 2(AWFOS-S2 The NFPA Diamond) \n
安全案例2——NFPA标签 66 \n
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第3章 RATE LAWS \n
速率方程 75 \n
3.1 Basic Definitions \n
基本定义 76 \n
3.1.1 Relative Rates of Reaction \n
相对反应速率 77 \n
3.2 The Rate Law \n
速率方程 78 \n
3.2.1 Power Law Models and Elementary Rate Laws \n
幂函数模型和基元反应速率方程 79 \n
3.2.2 Nonelementary Rate Laws \n
非基元反应速率方程 82 \n
3.2.3 Reversible Reactions \n
可逆反应 86 \n
3.3 The Reaction-Rate Constant \n
反应速率常数 89 \n
3.3.1 The Rate Constant k and Its Temperature Dependence \n
速率常数k和温度效应 89 \n
3.3.2 Interpretation of the Activation Energy \n
活化能的解释 90 \n
3.3.3 The Arrhenius Plot \n
阿伦尼乌斯公式 96 \n
3.4 Molecular Simulations \n
分子模拟 100 \n
3.4.1 Historical Perspective \n
历史回顾 100 \n
3.4.2 Stochastic Modeling of Reactions \n
反应的随机模型 101 \n
3.5 Present Status of Our Approach to Reactor Sizing and Design \n
反应器尺寸计算和设计的方法 103 \n
3.6 And Now… A Word from Our Sponsor—Safety 3(AWFOS-S3 The GHS Diamond) \n
安全案例3——GHS标签 104 \n
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第4章 STOICHIOMETRY \n
化学计量关系 117 \n
4.1 Batch Reactors (BRs) \n
间歇反应器（BRs） 119 \n
4.1.1 Batch Concentrations for the Generic Reaction, Equation (2-2) \n
常见反应的浓度关系式（2-2） 121 \n
4.2 Flow Systems \n
流动系统 125 \n
4.2.1 Equations for Concentrations in Flow Systems \n
流动系统浓度方程 126 \n
4.2.2 Liquid-Phase Concentrations \n
液相浓度 126 \n
4.2.3 Gas-Phase Concentrations \n
气相浓度 127 \n
4.3 Reversible Reactions and Equilibrium Conversion \n
可逆反应和平衡转化率 138 \n
4.4 And Now… A Word from Our Sponsor—Safety 4(AWFOS-S4 The Swiss Cheese Model) \n
安全案例4——瑞士奶酪模型 143 \n
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第5章 ISOTHERMAL REACTOR DESIGN: CONVERSION \n
等温反应器设计：转化率 155 \n
5.1 Design Structure for Isothermal Reactors \n
等温反应器的设计架构 156 \n
5.2 Batch Reactors (BRs) \n
间歇反应器（BRs） 160 \n
5.2.1 Batch Reaction Times \n
间歇反应器反应时间 161 \n
5.3 Continuous-Stirred Tank Reactors (CSTRs) \n
全混釜（CSTRs） 168 \n
5.3.1 A Single CSTR \n
单个全混釜 168 \n
5.3.2 CSTRs in Series \n
全混釜串联 171 \n
5.4 Tubular Reactors \n
管式反应器 178 \n
5.4.1 Liquid-Phase Reactions in a PFR υ = υ0 \n
平推流反应器中的液相反应υ = υ0 179 \n
5.4.2 Gas-Phase Reactions in a PFR [υ = υ0 (1 + εX) (T/T0)(P0/P)] \n
平推流反应器中的气相反应 [υ = υ0 (1 + εX) (T/T0)(P0/P)] 180 \n
5.4.3 Effect of ε on Conversion \n
ε对转化率的影响 180 \n
5.5 Pressure Drop in Reactors \n
反应器中的压降 185 \n
5.5.1 Pressure Drop and the Rate Law \n
压降和速率方程 185 \n
5.5.2 Flow Through a Packed Bed \n
填充床中的流动 187 \n
5.5.3 Pressure Drop in Pipes \n
管道中的压降 191 \n
5.5.4 Analytical Solution for Reaction with Pressure Drop \n
考虑压降的化学反应的解析解 194 \n
5.5.5 Robert the Worrier Wonders: What If… \n
Robert想知道，如果条件改变会发生什么 198 \n
5.6 Synthesizing the Design of a Chemical Plant \n
化工厂设计 208 \n
5.7 And Now… A Word from Our Sponsor—Safety 5 (AWFOS-S5 A Safety Analysis of the Incident Algorithm) \n
安全案例5——事故安全分析算法 210 \n
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第6章 ISOTHERMAL REACTOR DESIGN: MOLES AND MOLAR FLOW RATES \n
等温反应器设计：物质的量和摩尔流率 229 \n
6.1 The Moles and Molar Flow Rate Balance Algorithms \n
基于物质的量和摩尔流率的衡算方法 230 \n
6.2 Mole Balances on CSTRs, PFRs, PBRs, and Batch Reactors \n
全混釜、平推流、填充床和间歇反应器的摩尔衡算 230 \n
6.2.1 Liquid Phase \n
液相 230 \n
6.2.2 Gas Phase \n
气相 232 \n
6.3 Application of the PFR Molar Flow Rate Algorithm to a Microreactor \n
应用于微反应器的平推流反应器摩尔流率算法 234 \n
6.4 Membrane Reactors \n
膜反应器 239 \n
6.5 Unsteady-State Operation of Stirred Reactors \n
搅拌釜反应器的非稳态操作 248 \n
6.6 Semibatch Reactors \n
半间歇反应器 249 \n
6.6.1 Motivation for Using a Semibatch Reactor \n
使用半间歇反应器的目的 249 \n
6.6.2 Semibatch Reactor Mole Balances \n
半间歇反应器的摩尔衡算 249 \n
6.6.3 Equilibrium Conversion \n
平衡转化率 255 \n
6.7 And Now… A Word from Our Sponsor—Safety 6 (AWFOS-S6 The BowTie Diagram) \n
安全案例6——领结图 256 \n
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第7章 COLLECTION AND ANALYSIS OF RATE DATA \n
反应速率数据的收集和分析 269 \n
7.1 The Algorithm for Data Analysis \n
数据分析算法 270 \n
7.2 Determining the Reaction Order for Each of Two Reactants Using the Method of Excess \n
使用过量方法确定两个反应物的反应级数 272 \n
7.3 Integral Method \n
积分方法 273 \n
7.4 Differential Method of Analysis \n
微分方法 277
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